There are the 2099 characters, which included a Vulture 2099, a Venom 2099 and possibly others that I can't remember.
>
http://darkmark6.tripod.com/wonderind.htm
> Wonder Woman No. 96
> February 1958
>
> Story: “Prisoner of the Time Capsule†(8 pages)
> Editor: Whitney Ellsworth
> Writer: Robert Kanigher
> Artist: Harry G. Peter
> Feature Character: Wonder Woman
> Villain: Angle Man (last appearance in issue #92; next appears in issue #115), Angle Man of 4457 A.D. (First and only appearance)
>
> Wonder Woman No. 84
> August 1956
> Cover: Wonder Woman vs. humanoid Wonder Woman //Ross Andru / Mike Esposito
> Story: “The Secret Wonder Woman†(8 pages)
> Editor: Whitney Ellsworth
> Writer: Robert Kanigher
> Artist: Harry G. Peter
> Feature Character: Wonder Woman
> Villain: Angle Man (last appearance in issue #81; next appears in issue #92), a humanoid Wonder Woman (first appearance; destroyed in this story)
>
> Any MVL examples of future versions of established villains?
>
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